Amazia is a magical fantasy world of bright colors and fantastical creatures. It is a place where the Impossible becomes Possible. It has an ecosystem regulated by a rainbow, which controls the amount of glitter produced by the Glitterflies' wings. This glitter regulates the growth of Fluffy Flowers. And Fluffy Flower seeds turn into Jelly Trees, and Jelly trees make up Jelly Forests, which are crucial homes, and food sources, for the animals and other beings in Amazia. There are also forests of balloon trees, and at least one volcano. The series also features a mood willow tree that changes a character's hair color to suit their mood when they walk under it. Wiggly lily pads also react to characters' emotions. It also rains popcorn, butter, and salt.

01. "Amazing Amazia Rainbow" On her birthday, Luna receives a magic toy chest, which leads her to the enchanted world of Amazia and new best pals Bibi, Sammy, and Karoo.
02. "The Fuzzlings / Now We're Cooking" When three frightened fuzzlings go astray, Luna and her pals team up to find them. / Luna tests her leadership skills while filling in for Chef Zesto.
03. "Grumpy Volcano / Shadow Show" Cranky volcano Ashton refuses to erupt into fireworks, so Luna tries to cheer him up. / Luna plays detective after her three pals' shadows disappear.
04. "Star Dust / Popcorn Storm" Luna offers to clean Amazia's dusty stars, but can she restore their twinkle all by herself? / Luna helps Sammy conquer his fear of popcorn storms.
05. "The Crystal Queen / Seahorse Hero" At the queen's welcome party, Luna "assumes instead of asks" and chaos ensues. / When Bibi loses control of her giant seahorse, Luna leads the rescue.
06. "Lost Land / Boom Shine" Unaware that boy wizard Melvin has cast a spell, the crew gets stuck in Lost Land. / Zoom Shine tries a risky stunt after her showoff cousin goads her.
07. "The Show Must Go On / Great Train Chase" To create a show for the Queen, the Amazia pals try some teamwork. / When dizzy Karoo makes Sammy's train run wild, a special crew flies to the rescue.
08. "Wishy Swishy Wishing Well / Painting Day" Karoo causes the wishing well to explode, but Luna has a plan to fix it. / On Painting Day, Karoo mopes until his pals show him how to make art fun.
09. "Take Off Your Dancing Shoes / Dream Boat" To get shy Sammy to dance, Bibi gives him magic shoes, but is magic what he really needs? / Unable to sleep, Luna joins her pals on a dream boat trip.
10. "Sammy's Grammy / Melvin's Magical Mix-up" The crew helps Sammy entertain his quiet grandma during her Amazia visit. / When Melvin's magic fails, the pals must convince him to accept their help.
11. "Happy Jollydays" Luna learns all about Jollydays in Amazia, but can she save the holidays after she breaks the Jolly Clause rule and makes her pals' gifts disappear?